Hello,
Modbus Serial master and Modbus gateway are two different functions.
Modbus serial master is a function, which allows user to configure periodical data collection from connected serial devices and send to server via HTTP(S) or MQTT. External Modbus TCP master commands cannot be routed to this function.
If you want to send Modbus TCP request to Modbus RTU devices, then you have to use RS485 Modbus gateway mode, which is located in Services -> RS232/RS485 -> RS485
Only Modbus serial master buffers collected data in RAM, since it does not need external requests to read data from connected slave devices.
I hope that I have answered your question. If not, please let me know what I have missed.