The other suggestion involves CLI/SSH manipulation and was already provided here. Please try it, if you want to continue using current firmware.
Otherwise, the device will be completely wiped after update with Keep settings set to off.
Updating with Keep settings set to on might result in your other configurations not working correctly.
The difference between firmware versions is quite significant, migration and configuration compatibility issues are likely to arise, but update should solve your PPPoE issue, as the issue was supposed to be solved with 7.2 firmware release.
You could make a backup of your current config, and only move files saved in backup's /etc/config directory to the same directory within the router after update.
There were also issues with backups size increasing after each time the backup is generated, so there is a likelihood that latest generated backup contains other backups within itself, which could be deleted to reduce it's size.
Also, a gradual update with Keep settings can be attempted in the following sequence:
7.01 -> 7.01.2 -> 7.01.4 -> 7.2.
Best regards,